![Two novel polyoxometalate (POM)-based metal–organic frameworks (MOFs), [TBA]3[ε-PMoV8MoVI4O36(OH)4Zn4][BTB]4/3·xGuest (NENU-500, BTB = benzene tribenzoate, TBA+ = tetrabutylammonium ion) and [TBA]3[ε-PMoV8MoVI4O37(OH)3Zn4][BPT] (NENU-501, BPT = [1,1′-biphenyl]-3,4′,5-tricarboxylate), were isolated. In these compounds, the POM fragments serving as nodes were directly connected with organic ligands](http://0.ss.508sys.com/image/loading/dot.gif "Two novel polyoxometalate (POM)-based metal–organic frameworks (MOFs), [TBA]3[ε-PMoV8MoVI4O36(OH)4Zn4][BTB]4/3·xGuest (NENU-500, BTB = benzene tribenzoate, TBA+ = tetrabutylammonium ion) and [TBA]3[ε-PMoV8MoVI4O37(OH)3Zn4][BPT] (NENU-501, BPT = [1,1′-biphenyl]-3,4′,5-tricarboxylate), were isolated. In these compounds, the POM fragments serving as nodes were directly connected with organic ligands")
Two novel polyoxometalate (POM)-based metal–organic frameworks (MOFs), [TBA]3[ε-PMoV8MoVI4O36(OH)4Zn4][BTB]4/3·xGuest (NENU-500, BTB = benzene tribenzoate, TBA+ = tetrabutylammonium ion) and [TBA]3[ε-PMoV8MoVI4O37(OH)3Zn4][BPT] (NENU-501, BPT = [1,1′-biphenyl]-3,4′,5-tricarboxylate), were isolated. In these compounds, the POM fragments serving as nodes were directly connected with organic ligands
Kinetically tuned dimensional augmentation as a versatile synthetic route towards robust metal–organic frameworks
05/16
2019
J. Am. Chem. Soc. 2015, 137, 7169–7177.
05/16
2019
Nat. Commun. 2014, 5, 5723.
05/16
2019
Chem. Soc. Rev., 2009,38, 1477-1504
|
|